27-Jan-22
Researchers from the University of Birmingham, U.K., and Duke University, U.S., have created a new family of polymers from sustainable sources that retain all of the same qualities as common plastics, but are also degradable and mechanically recyclable.
The scientists used sugar-based starting materials rather than petrochemical derivatives to make two new polymers, one which is stretchable like rubber and another which is tough but ductile, like most commercial plastics.
The researchers made the new polymers using isoidide and isomannide as building blocks. Both these compounds are made from sugar alcohols and feature a rigid ring of atoms. The researchers found that the isoidide-based polymer, showed a stiffness and malleability similar to common plastics, and a strength that is similar to high grade engineering plastics such as Nylon-6. Despite isoidide and isomannide only differing by the 3D spatial orientation of two bonds, known as stereochemistry, the isomannide-based material had similar strength and toughness but also showed high elasticity, recovering its shape after deformation. Notably, the materials retained their excellent mechanical properties following pulverisation and thermal processing, which is the usual method for mechanically recycling plastics.
Cutting edge computational modelling simulated how the polymer chains pack and interact to produce such different polymer properties. The unique 3D shapes of the sugar derivatives facilitate different movements and interaction of the long chains causing the huge difference in physical properties that was observed.
By creating copolymers that contain both isoidide and isomannide units, the researchers found that they could control the mechanical properties and degradation rates independently of one another. Hence, this system opens the door to using the unique shapes of sugars to independently tune the degradability for a specific use without significantly altering the properties of the material.
The chemical similarity of the polymers means that, unlike a lot of current commodity plastics, they can be blended together to yield materials with comparable or improved properties.
Dr Josh Worch, from Birmingham’sSchool of Chemistry, and a co-author in the research said: “The ability to blend these polymers together to create useful materials, offers a distinct advantage in recycling, which often has to deal with mixed feeds”.
Source: University of Birmingham
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